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Essentials of Chemical Reaction Engineering, 2nd Edition Solution Manual

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    Solutions Manual for Essentials of Chemical Reaction Engineering Second Edition H. Scott Fogler Ame and Catherine Vennema Professor of Chemical Engineering and The Arthur F. Thurnau Professor at the University of Michigan, Ann Arbor, Michigan

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    Table of Contents Screen Shot of Web Home Page .......................................................................................... i Screen Shot of Interactive Computer Games (ICGs) .......................................................... ii Algorithm to Decode ICGs ................................................................................................. v Screen Shot of Polymath Living Example Problems (LEPs)........................................... viii Sample Course Syllabus...................................................................................................... x Solutions to Chapter 1, Problems P1-1 through P1-8 Solutions to Chapter 2, Problems P2-1 through P2-10 Solutions to Chapter 3, Problems P3-1 through P3-15 Solutions to Chapter 4, Problems P4-1 through P4-10 Solutions to Chapter 5, Problems P5-1 through P5-26 Solutions to Chapter 6, Problems P6-1 through P6-13 Solutions to Chapter 7, Problems P7-1 through P7-11 Solutions to Chapter 8, Problems P8-1 through P8-18 Solutions to Chapter 9, Problems P9-1 through P9-21 Solutions to Chapter 10, Problems P10-1 through P10-23 Solutions to Chapter 11, Problems P11-1 through P11-10 Solutions to Chapter 12, Problems P12-1 through P12-27 Solutions to Chapter 13, Problems P13-1 through P13-9

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    i WEB HOME PAGE

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    ii INTERACTIVE COMPUTER GAMES (ICGs)

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    iii

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    iv

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    v ALGORITHM TO DECODE ICGs **** CONFIDENTIAL **** UNIVERSITY OF MICHIGAN INTERACTIVE COMPUTER MODULES FOR CHEMICAL ENGINEERING CHEMICAL REACTION ENGINEERING MODULES H. Scott Fogler, Project Director M. Nihat Gürmen, Project Manager (2002-2004) Susan Montgomery, Project Manager (1991-1993) Department of Chemical Engineering University of Michigan Ann Arbor, MI 48109-2136 ©2005 Regents of the University of Michigan - All Rights Reserved - INTERPRETATION OF PERFORMANCE NUMBERS Students should record their Performance Number for each program, along with the name of the program, and turn it in to the instructor. The Performance Number for each program is decoded as described in the following pages. The official site for the distribution of the modules is http://www.engin.umich.edu/~cre/icm Please report problems to icm.support@umich.edu.

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    vi ICMs with Windows ® interface Module Format Interpretation Example KINETIC CHALLENGE I CzBzzAzz Score = 1.5 * AB.C Perf. No. = 7 5 2 41 6 92 z = random numbers Score = 1.5*(62.7) = 94 % Note: 75% constitutes mastery. KINETIC CHALLENGE II CzBzzAzz Score = 2.0 * AB.C Perf. No. = 0 3 7 76 4 67 z = random numbers Score = 2.0*(47.0) = 94 % Note: 75% constitutes mastery. MURDER MYSTERY zzAzz A even: Killer and victim Perf. No. = 50 7 32 correctly identified Score: No credit A odd: Killer and victim not identified z = random numbers Note: An even number for the middle digit constitutes mastery. TIC TAC TOE zDzCzBzA Score = 4.0 * AB.C Perf. No. = 77803581 z = random numbers Score = 4*(15.0) = 60 configuration 7 completed Configurations X X X X X X X X X Note: Student receives 20 points for every square answered correctly. A score of 60 is needed for mastery of this module. GREAT RACE zzzCzABz Score = 6.0 * AB.C Perf. No. = 77738078 z = random numbers Score = 6*(07.3) = 44 Note: A score of 40 is needed for mastery of this module. 1 2 3 6 5 4 8 7 **** CONFIDENTIAL ****

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    vii ECOLOGY AzBCzaaD z = random numbers a = random characters A gives info on r^2 value of the student’s linearized plot A=Y if r^2 >= 0.9 A=A if 0.9 > r^2 >= 0.8 A=X if 0.8 > r^2 >= 0.7 A=F if 0.7 > r^2 A=Q if Wetland Analysis/Simulator portion has not been completed B gives info on alpha B=1 to 4 => student's alpha < (simulator's alpha  0.5) B=5 to 9 => student's alpha > (simulator's alpha  0.5) B=X if Wetland Analysis/Simulator portion has not been completed C indicates number of data points deactivated during analysis C=number of deactivated data points if at least 1 point has been deactivated C=a randomly generated letter from A to Y if 0 points deactivated C=Z if Wetland Analysis/Simulator portion has not been completed D gives info on solution method used by student D=1 if polynomial regression was used D=2 if differential formulas were used D=3 if graphical differentiation was used D=4 to 9 if Wetland Analysis/Simulator portion has not been completed Perf No. = A7213DF2 1) A => 0.9 > r^2 >= 0.8 2) 2 => student’s alpha < (simulator’s alpha  0.5) 3) 1 => one data point was deactivated 4) 2 => differential formulas were used STAGING zCBzAFzED z = random numbers Perf. No. = 2 12 5 4 8 2 9 13 Final conversion = 2*AB.C conversion = 2*42.1 = 84.2 Final flow rate = 2*DE.F flow rate = 2*31.2 = 62.4 Please make a pass/fail criterion based on these values. **** CONFIDENTIAL ****

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    viii ICMs with Dos ® interface Module Format Interpretation Example HETCAT zzABzCD A=2,3,5,7: interaction done Perf. No. = 80 27 4 35 B=2,3,5,7: intro done A: Worked on interaction C=2,3,5,7: review done B: Looked at intro D denotes how much they C: Looked at review did in the interaction: D: found parameter values, didn’t find mechanism D<2 Not done 2 < D:5 4 Dependences 4 < D:5 6 Parameter values 6<D Mechanism z = random numbers Note: Performance number given only if student goes through the interaction portion of the module HEATFX1 zzAzz A even: score > 85 % Perf. No. = 53 6 07 z = random numbers Score > 85 % Note: Student told they have achieved mastery if their score is greater than 85% HEATFX2 zzzAzz A even: completed interaction Perf. No. = 407 5 82 z = random numbers Interaction not completed Note: Performance number given only if student goes through the interaction portion of the module. **** CONFIDENTIAL ****

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    ix LIVING EXAMPLE PROBLEMS (LEPs)

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    x SAMPLE COURSE SYLLABUS ChE 344: CHEMICAL REACTION ENGINEERING Fundamentals of chemical reaction engineering. Rate laws, kinetics, and mechanisms of homogeneous and heterogeneous reactions. Analysis of rate data, multiple reactions, heat effects, bioreactors. Design of industrial reactors. Prerequisite: ChE 330, ChE 342 Fall 2015 Lectures: M,W 8:40 (Sharp) to 10:30 (not so sharp) – Room: 1013 Dow Instructor: Professor H. Scott Fogler 3168 DOW, 763-1361, sfogler@umich.edu Office Hours: M,W 10:30a to 11:30a Course assistants include: Instructional aids, tutor, proctors, and graders Text Required Elements of Chemical Reaction Engineering , 5 th edition, H. Scott Fogler Web site: www.umich.edu/~elements/5e Recommended Reading List • Problem Solving in Chemical and Biochemical Engineering with POLYMATH, Excel, and MATLAB , 2nd Edition 2008, Cutlip & Shacham • The Elements of Style , Strunk and White • Strategies for Creative Problem Solving , 3rd Edition 2014, Fogler, LeBlanc & Rizzo (for OEP’s) Schedule *Note - all ICGs (Interactive Computer Games) are Individual* 1) Wednesday, September 9 Topic: Lecture 1 – Chapter 1, Introduction, POLYMATH, Mole balances Read: Preface, Prerequisites, Appendix B In-Class Problem: No In-Class Problem 2) Monday, September 14 Topic: Lecture 2 – Chapter 2, Design equations, Levenspiel plots, Reactor staging Read: Chapter 1, P1-9 A , Appendix A, from the Web Chapter 2, Sections 2.1, 2.2, and 2.3 Hand In: Problem Set 1: P1-1 A , P1-6 B In-Class Problem: 1 Study Problems: P1-8 A 3) Wednesday, September 16 Topic: Lecture 3 – Chapter 3, Rate laws Read: Chapter 2, Chapter 3 Hand In: Problem Set 2: Define terms in the Arrhenius Equation, P2-2 A , Intro to Learncheme In-Class Problem: 2 ( Hint: Viewing the University of Alabama YouTube video “The Black Widow” noted in Problem P3-8 B may help you with today's in class problem)

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    xi Study Problems: P2-7 A 4) Monday, September 21 Topic: Lecture 4 – Chapter 4, Stoichiometry Batch Systems Read: Chapter 4 Section 4.1 Hand In: Problem Set 3: Define θ i , θ A , θ B , and δ , P2-10 B , P3-5 A , P3-8 B , P3-11 B , P3-13 A In-Class Problem: 3 - Bring i>clickers (tentative) - Test Run of System in 2166 Dow Study Problems: P3-14 A 5) Wednesday, September 23 Topic: Lecture 5 – Chapter 4, Stoichiometry Flow Systems Read: Chapter 4, Section 4.1 Hand In: Problem Set 4: Define ε , F T0 , C T0 , P4-2 A . In-Class Problem: 4 Study Problems: P4-1 A parts (c) and (d) 6) Monday, September 28 Topic: Lecture 6 – Chapter 5, Isothermal reactor design Read: Chapter 5, Chapter 5 Summary Notes on the Web site Hand In: Problem Set 5: P4-1 A (a) and (b) only, P4-3 A , P4-4 B , P4-5 B . In-Class Problem: 5 Study Problems: P4-10 C 7) Wednesday, September 30 Topic: Lecture 7 – Chapter 5, California Registration Exam Problem Hand In: Problem Set 6: What are you asked to find P5-18 B ? What is the Ergun Equation? P5-2 A . In-Class Problem: 6 Study Problems: P5-1 B (a) and (b) 8) Monday, October 5 Topic: Lecture 8 – Chapter 5, Pressure drop Read: Chapter 5, Sections 5.4 and 5.5 Hand In: Problem Set 7: P5-3 A , P5-4 B , P5-5 A , P5-8 B , P5-13 B omit parts (j) and (k), P5-16 B (a). In-Class Problem: 7 – Bring Laptops Study Problems: P5-9 A , P5-10 B (a). 9) Wednesday, October 7 Topic: Lecture 9 – Chapter 6, Membrane Reactors Read: Chapter 6 Hand In: Problem Set 8: P5-13 B part (j) and (k), P5-22 A . In-Class Problem: 8 – Bring Laptops Study Problems: P5-21 B 10) Monday, October 12 Topic: Lecture 10 – Chapter 6, Semibatch Reactors Read: Chapter 6 Hand In: Problem Set 9: P5-1 A (a), P5-11 B , P6-4 B delete part (c), P6-5 B . In-Class Problem: 9 – Bring Laptops to carry out Polymath ODE Solver Study Problems: P6-7 B

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    xii 11) Wednesday, October 14 Topic: Lecture 11 – Chapter 7, Analysis of Rate Data/Chapter 9, Pseudo Steady State Read: Chapter 7, Chapter 9, Section 9.1 and the cobra web module Hand In: Problem Set 10: LEP for Example 6-1, P6-2 B , P6-11 B omit part (c) In-Class Problem: 10 – Bring Laptops to carry out Polymath Regression Study Problems: P7-6 B . 12) Monday, October 19 Topic: No Classes – Fall Study Break 13) Wednesday, October 21 Topic: Lecture 12 – Chapter 8, Multiple Reactions Read: Chapter 8, Sections 8.1, 8.2, 8.3 and 8.4; Hand In: Problem Set 11: P7-7 A , P7-8 A . In-Class Problem: 11 Study Problems P7-10 A 14) Monday, October 26 Topic: Lecture 13 – EXAM I – Covers Chapters 1 through 7 Closed book, web, notes, in-class problems and home problems. 15) Wednesday, October 28 Topic: Lecture 14 – Chapter 8: Multiple Reactions Read: Chapter 8, Sections 8.5, 8.6, 8.7 and 8.8 In-Class Problem: 12 – Bring Laptops Hand In: Problem Set 12: P8-1 A (a) part (1) only, P8-1 A (b), P8-1 A (c) part (1) only, P8-2 B , P8-6 B , P8-7 C (a), (b) and (c) Study Problems P8-10 B 16) Monday, November 2 Topic: Lecture 15 – Derivation of Energy Balance Read: Chapter 11, Sections 11.1, 11.2 and 11.3 Hand In: Problem Set 13: P8-12 B . Comprehensive Problem In-Class Problem: 13 – Bring Laptops Study Problems: P8-16 A 17) Wednesday, November 4 Topic: Lecture 16 – Chapter 11: Adiabatic Equilibrium Conversion and Reactor Staging Read: Finish Reading Chapter 11, Equilibrium conversion appendix In-Class Problem: 14 Study Problems P11-6 B 18) Monday, November 9 Topic: Lecture 17 – Heat Exchange, Adiabatic Reactors ICPs Read: Chapter 12 Sections 12.1 through 12.2 Hand In: Problem Set 14: P11-1 A (b), P11-3 B , P11-4 A . In-Class Problem: 15 Study Problem: P12-6 A

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    xiii 19) Wednesday, November 11 Topic: Lecture 18 – Trends in Conversion and Temperature Profiles Applications of the Energy Balance to PFRs Read: Chapter 12, Section 12.3 and 12.4 Hand In: Problem Set 15: P12-3 B LEP In-Class Problem: 16 – Bring Laptops 20) Monday, November 16 Topic: Lecture 19 – Multiple Reactions with Heat Effects This topic is a major goal of this course, to carry out calculations for non isothermal multiple reactions. Applications of the Energy Balance to PFRs Hand In: Problem Set 16: P12-4 A (a) and (b), P12-14 B , P12-17 B , P12-21 B . In-Class Problem: 17 – Bring Laptops Study Problem: P12-19 B , i>clicker questions handed out in class 21) Wednesday, November 18 Topic: Lecture 20 – CSTR and Review for Exam II 22) Monday, November 23 Topic: Lecture 21 – EXAM II – Chapters 8, 11 and 12. Book and notecard are the only materials allowed Hand In: Problem Set 17: P12-26 C 23) Wednesday, November 25 Topic: Lecture 22 – Multiple Steady States (MSS) Multiple Reactions with Heat Effects Read: Sections 12.6 and 12.7 In-Class Problem: 18 – Bring a Ruler/Straight Edge Study Problems: P13-4 B 24) Monday, November 30 Topic: Lecture 23 – Safety (CSI) Read: Chapter 13 Hand In: Problem Set 18: P13-1 B (b) and (f), P13-8 B In-Class Problem: 19 – Bring Laptops Study Problems: P13-4 B 25) Wednesday, December 2 Topic: Lecture 24 –Catalysis Reactor Safety Read: Chapter 13, Sections 13.1 through 13.3, and 13.5 Hand In: Problem Set 19: P10-2 A part (d), P10-4 B In-Class Problem: 20 Study Problems: P12-16 B 26) Monday, December 7 Topic: Lecture 25 – Catalysis Read: Chapter 10, Sections 10.1 through 10.2.2 Hand In: Problem Set 20: P10-3 A , P10-8 B , P10-10 B In-Class Problem: 21 Study Problems: P10-7 B , P10-9 B

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