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20. Sodium azide, $\mathrm{NaN}_{3}$ is best known as the chemical found in automobile airbags. When the car undergoes a head-on collision, chemical reactions occur inside the gas generator will generate nitrogen gas $\left(\mathrm{N}_{2}\right)$ by the rapid decomposition of $\mathrm{NaN}_{3}$ to fill the airbag. 2 \mathrm{NaN}_{3}(\mathrm{~s}) \rightarrow 2 \mathrm{Na}(\mathrm{~s})+ 3 \mathrm{~N}_{2}(\mathrm{~g}) For the air bag to operate correctly, calculate the amount (mass) of $\mathrm{NaN}_{3}$ needed in the gas generator to generate $\mathrm{N}_{2}$ gas that is completely fill 65 L of nylon airbag to a pressure of 980 mmHg at $25.0^{\circ} \mathrm{C}$.
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Step 1:
: Convert the pressure from mmHg to atm.

We know that: 1 atm = 760 mmHg So, 980 mmHg = 980 / 760 = 1.2895 atm (approximately)

Step 2:
: Use the ideal gas law to calculate the number of moles of N^2 gas.

The ideal gas law is given by: PV = nRT Where: - P is the pressure - V is the volume - n is the number of moles - R is the gas constant - T is the temperature in Kelvin First, convert the temperature to Kelvin: T = 25.0^{\circ} \mathrm{C} + 273.15 = 298.15 \mathrm{~K} Now, we can calculate the number of moles of N^2 gas:

Step 3:
: Calculate the number of moles of NaN^3 required.

From the chemical equation, we know that 2 moles of NaN^3 produce 3 moles of N^2 gas. Therefore, we can calculate the number of moles of NaN^3 required as follows:

Step 4:
: Convert the number of moles of NaN^3 to mass.

The molar mass of NaN^3 is 65.0 g/mol. Therefore, the mass of NaN^3 required is: m_{\mathrm{NaN}_{3}} = n_{\mathrm{NaN}_{3}} \times \text{molar mass of NaN}_{3} = 0.223 \mathrm{~mol} \times 65.0 \mathrm{~g/mol} = 14.495 \mathrm{~g}

Final Answer

The amount of NaN^3 required is 14.495 g (approximately).