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QuestionChemistry

"According to VSEPR theory, what is the shape of a molecule of CS^2? A. Bent B. Trigonal-planar C. Tetrahedral D. Linear "
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Answer

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Step 1:
I'll solve this step by step using the VSEPR (Valence Shell Electron Pair Repulsion) theory guidelines:

Step 2:
: Determine the central atom

- In CS^2, carbon (C) is the central atom

Step 3:
: Count the total number of valence electrons

- Total valence electrons: $$4 + 12 = 16$$ electrons
- Carbon: 4 valence electrons - Sulfur (S): 6 valence electrons × 2 = 12 valence electrons

Step 4:
: Draw the Lewis structure

- Electron domain geometry: $$4$$ domains = tetrahedral electron geometry
- Carbon will form double bonds with each sulfur atom - Electron arrangement: 4 electron domains around carbon

Step 5:
: Determine molecular geometry

- All 4 electron domains are bonding domains - No lone pairs on the central carbon - Bonds are arranged linearly (180° apart)

Step 6:
: Apply VSEPR theory rules

- Linear arrangement of atoms - No lone pairs - Symmetrical electron distribution

Final Answer

Linear Explanation: The molecule CS^2 has a linear shape because the two sulfur atoms are positioned 180° apart from the central carbon atom, with no lone pairs present.