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Please show work. Lewis Dot Structure: Electron Pair Geometry Molecule Shape Polar/Nonpolar For H^2Se: 1) i) What type of intermolecular forces are between molecules of H^2Se? Explain WHY. ii) Which would have the higher boiling point, H^2Se or H^2O? Explain WHY.
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Step 1:
I'll solve this step by step, focusing on the Lewis dot structure and intermolecular forces for H^2Se.

Step 2:
: Lewis Dot Structure Analysis

- Total valence electrons: $$6 + (2 \times 1) = 8$$ electrons
- Selenium (Se) is in Group 16 (VIA), has 6 valence electrons - Hydrogen (H) has 1 valence electron - Central atom is Se - Structure will be H-Se-H with two lone pairs on Se

Step 3:
: Electron Pair Geometry

- $$AX_{2}E_{2}$$ molecular geometry
- Central Se has 4 electron domains (2 bonding, 2 non-bonding) - Electron pair geometry is tetrahedral - Bent molecular shape (due to lone pairs)

Step 4:
: Intermolecular Forces in H^2Se

- Primarily weak van der Waals (London dispersion) forces - Reasons:

Step 5:

Molecule is non-polar but has temporary induced dipoles

Step 6:

Larger molecular weight increases dispersion forces

Step 7:

Weak hydrogen bonding possible, but much weaker than H^2O

Step 8:
: Boiling Point Comparison

- H^2O has stronger hydrogen bonding - Hydrogen bonds in H^2O are much stronger than London forces in H^2Se - Therefore, H^2O will have a higher boiling point

Final Answer

i) Intermolecular forces: Primarily London dispersion forces ii) H^2O would have the higher boiling point due to strong hydrogen bonding