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QuestionChemistry

What are the electron and molecular geometries, respectively, for iodine trifluoride, IF^3? A. Electron geometry is trigonal bipyramidal. Molecular geometry is trigonal planar. B. Electron geometry is trigonal bipyramidal. Molecular geometry is T-shaped. C. Electron geometry is octahedral. Molecular geometry is T-shaped. D. Electron geometry is trigonal planar. Molecular geometry is trigonal bipyramidal.
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Answer

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Step 1:
Let's solve this step by step using VSEPR (Valence Shell Electron Pair Repulsion) theory:

Step 2:
: Determine the central atom and total valence electrons

- Total valence electrons: $$7 + (3 \times 7) = 28$$ electrons
- Central atom is Iodine (I) - Fluorine atoms (F) contribute 7 valence electrons each - Iodine contributes 7 valence electrons

Step 3:
: Draw the Lewis structure

- Iodine forms single bonds with three fluorine atoms - Iodine will have two lone pairs - Total electron domains: 5 (3 bonding, 2 non-bonding)

Step 4:
: Determine electron geometry

- 5 total electron domains - Electron geometry is trigonal bipyramidal - This means the electron domains are arranged to minimize repulsion

Step 5:
: Determine molecular geometry

- 3 bonding domains, 2 lone pairs - Lone pairs occupy equatorial positions to minimize repulsion - Resulting molecular geometry is T-shaped

Step 6:
: Analyze the options

- Option B matches our analysis: * Electron geometry is trigonal bipyramidal * Molecular geometry is T-shaped

Final Answer

Electron geometry is trigonal bipyramidal. Molecular geometry is T-shaped.