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QuestionChemistry

"What is the electron geometry and molecular shape of carbon tetrabromide (CBr4) without making a model? Do you expect the bonds in this molecule to be polar?"
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Answer

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Step 1:
Let's solve this step by step:

Step 2:
: Determine the central atom and valence electrons

- Total valence electrons: $$4 + (4 \times 7) = 32$$ electrons
- The central atom is carbon (C) - Carbon has 4 valence electrons - Each bromine (Br) contributes 7 valence electrons

Step 3:
: Draw the Lewis structure

- Carbon will form 4 single bonds with bromine atoms - Each Br atom will complete its octet - All 32 valence electrons will be used in bonding

Step 4:
: Determine electron domain geometry

- $$\text{Electron geometry} = \text{Tetrahedral}
- Carbon has 4 single bonds - Using VSEPR theory, this means 4 electron domains around the central carbon - The electron geometry is tetrahedral

Step 5:
: Determine molecular shape

- $$\text{Molecular shape} = \text{Tetrahedral}
- All 4 electron domains are bonding domains - No lone pairs on the central carbon

Step 6:
: Analyze bond polarity

- $$\text{Net molecular polarity} = \text{Nonpolar}
- C-Br bonds are polar due to electronegativity difference - However, the tetrahedral symmetry means these polar bonds cancel out

Final Answer

- Electron geometry: Tetrahedral - Molecular shape: Tetrahedral - Molecular polarity: Nonpolar (despite polar C-Br bonds)