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QuestionChemistry

What is the molecular configuration of nitrogen trifluoride (NF3)? A. Linear B. Trigonal Planar C. Tetrahedral D. Octahedral
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Answer

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Step 1:
I'll solve this step by step using VSEPR theory to determine the molecular configuration of nitrogen trifluoride (NF3).

Step 2:
: Determine the central atom

- The central atom is nitrogen (N) - Nitrogen will form bonds with three fluorine atoms

Step 3:
: Count valence electrons

- Total valence electrons: $$5 + (7 \times 3) = 26$$ electrons
- Nitrogen (Group 5A): 5 valence electrons - Fluorine (Group 7A): 7 valence electrons × 3 = 21 electrons

Step 4:
: Draw Lewis structure

- Three single bonds between N and F - Remaining electrons form lone pairs on nitrogen - Nitrogen has one lone pair of electrons

Step 5:
: Apply VSEPR theory

- Total electron domains: 4 (3 bonding + 1 lone pair) - Electron domain geometry: Tetrahedral - Molecular geometry: Trigonal pyramidal

Step 6:
: Determine molecular configuration

- The presence of a lone pair distorts the perfect tetrahedral shape - Molecular shape is trigonal pyramidal

Final Answer

Tetrahedral Explanation: While the electron domain geometry is tetrahedral, the actual molecular configuration is trigonal pyramidal due to the lone pair on nitrogen, which makes the answer C. Tetrahedral.