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QuestionChemistry

What is the molecular geometry for NO^2 -? A. Trigonal planar B. Bent C. Trigonal pyramidal D. Linear
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Answer

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Step 1:
I'll solve this step by step using VSEPR theory to determine the molecular geometry of NO^2 -.

Step 2:
: Determine the number of valence electrons

- Total valence electrons: $$5 + 12 + 1 = 18$$ electrons
- Nitrogen (N): 5 valence electrons - Oxygen (O): 6 × 2 = 12 valence electrons - Extra electron from negative charge: + 1

Step 3:
: Draw the Lewis structure

- Central nitrogen atom - Two oxygen atoms bonded to nitrogen - Negative charge distributed - Total electron domains: 3 (2 single bonds, 1 lone pair)

Step 4:
: Analyze electron domain geometry

- 3 total electron domains - Electron domain geometry: Trigonal planar - Lone pair present on central nitrogen

Step 5:
: Determine molecular geometry

- With 3 electron domains and 1 lone pair - Actual molecular geometry is BENT - Bond angle will be less than 120° due to lone pair repulsion

Step 6:
: Evaluate answer choices

- A. Trigonal planar ❌ - B. Bent ✅ - C. Trigonal pyramidal ❌ - D. Linear ❌

Final Answer

Bent