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QuestionChemistry

What is the molecular geometry of carbon tetrachloride, CCl₄, and the molecular geometry at the central atom in Cl₂CO? A. trigonal planar B. trigonal pyramidal C. square planar D. tetrahedral E. bent
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Answer

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Step 1:
Let's solve this step by step:

Step 2:
: Analyze Carbon Tetrachloride (CCl₄)

- First, draw the Lewis structure of CCl₄ - Carbon is the central atom - Carbon has 4 chlorine atoms bonded to it - Determine electron geometry and molecular geometry - Carbon has 4 bonding pairs and 0 lone pairs - This results in a tetrahedral electron geometry - The molecular geometry is also tetrahedral

Step 3:
: Analyze Dichlorocarbonyl (Cl₂CO)

- Draw the Lewis structure of Cl₂CO - Carbon is the central atom - Carbon is bonded to: * 2 chlorine atoms * 1 oxygen atom with a double bond * 1 hydrogen atom (not shown in the original notation) - Determine electron geometry and molecular geometry - Carbon has 3 bonding pairs and 0 lone pairs - This results in a trigonal planar geometry

Step 4:
: Compare to Given Options

- CCl₄ matches option D: tetrahedral - Cl₂CO matches option A: trigonal planar

Final Answer

D. tetrahedral (for CCl₄)