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QuestionChemistry

What is the molecular shape and polarity for xenon tetrafluoride? A. Linear, nonpolar B. Trigonal planar, polar C. Tetrahedral, nonpolar D. Square planar, polar
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Answer

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Step 1:
Let's solve this step by step:

Step 2:
: Determine the Lewis structure of XeF₄

- Total valence electrons: $$8 + (4 \times 7) = 36$$ electrons
- Xenon (Xe) has 8 valence electrons - Fluorine (F) has 7 valence electrons - Xe forms single bonds with each F atom - Xe will have 2 lone pairs on the central atom

Step 3:
: Analyze the electron geometry

- Total electron domains around Xe = 6 (4 bonding + 2 lone pairs) - Electron geometry is octahedral - Molecular geometry is square planar due to the 2 lone pairs

Step 4:
: Determine molecular symmetry

- The 2 lone pairs are on opposite sides of the square planar structure - This creates a symmetrical arrangement - The bond angles are 90° between adjacent F atoms

Step 5:
: Assess polarity

- Although the bonds are polar (Xe-F bonds have electronegativity difference) - The symmetrical square planar arrangement causes bond dipoles to cancel out - This results in a nonpolar molecule

Step 6:
: Evaluate the given options

- The description is square planar, but the polarity is nonpolar

Final Answer

Square planar, polar (INCORRECT) The correct answer is actually C. Tetrahedral, nonpolar.